GOLD CHEMISTRY
1995 - 2000

 

"Auriophilicity in Polynuclear (Phosphane)gold(I) Thiolates {Me3CS[Au(PPh3)]2}+ BF4- and {(CH2S)2[Au(PPh3)]3}+ BF4-"
A. Sladek, H. Schmidbaur, Chem. Ber. 128, 907-909 (1995).

"Synthesis and Structure of a Cyclic Complex of Digold Sulfide Au2S and of Related Compounds"
S. Hofreiter, M. Paul, H. Schmidbaur, Chem. Ber. 128, 901-905 (1995).

"Sodium Tetraphenylborate as a phenylating agent for gold(I) complexes"
A. Sladek, S. Hofreiter, M. Paul, H. Schmidbaur, J. Organomet. Chem. 501, 47-51 (1995).

"Hypercoordinate Carbon in Protonated Tetraauriomethane Molecules"
H. Schmidbaur, F.P. Gabbaï, A. Schier, J. Riede, Organometallics 14, 4969-4971 (1995).

"Coordination Chemistry of Dimethylgold Halides with Bidentate Phosphorus and Arsenic Ligands - Revisited"
M. Paul, H. Schmidbaur, Chem. Ber. 129, 77-83 (1996).

"Dendrimer-Based Multinuclear Gold(I) Complexes"
P. Lange, A. Schier, H. Schmidbaur, Inorg. Chem. 35, 637-642 (1996).

"Gold(I) clustering at the triphenylphosphinimine nitrogen atom"
A. Bauer, F. Gabbaï, A. Schier, H. Schmidbaur, Phil. Trans. R. Soc. Lond. A 354, 381-394 (1996).

"Isolation and Structural Characterization of [P(AuPPh3)5][BF4]2 via Cleavage of a P-P Bond by Cationic Gold Fragments: Direct Evidence of the Structure of the Elusive Tetrakis[phosphineaurio(I)]phosphonium(+) Cation"
R.E. Bachman, H. Schmidbaur, Inorg. Chem. 35, 1399-1401 (1996).

"Ligand Influences on the Supramolecular Chemistry of Simple Gold(I) Complexes: Mononuclear (Isonitrile)gold(I) Complexes"
W. Schneider, K. Angermaier, A. Sladek, H. Schmidbaur, Z. Naturforsch. 51b, 790-800 (1996).

"Polynuclear Gold(I) Complexes of Mercaptocarboxylic Acids"
A. Sladek, W. Schneider, K. Angermaier, A. Bauer, H. Schmidbaur, Z. Naturforsch. 51b, 765-772 (1996).

"Polynuclear Gold Complexes of the Carbodiimide [N=C=N]2-"
W. Schneider, K. Angermaier, H. Schmidbaur, Z. Naturforsch. 51b, 801-805 (1996).

"Preparation and Structure of Poly(gold)telluronium Salts"
K. Angermaier, H. Schmidbaur, Z. Naturforsch. 51b, 879-882 (1996).

"Vibrational and solid-state phosphorus-31 nuclear magnetic resonance spectroscopic studies of 1:1 complexes of PPh3 with gold(I) halides; crystal structure of [AuBr(PMe3)] "
K. Angermaier, G.A. Bowmaker, E.N. de Silva, P.C. Healy, B.E. Jones, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1996, 3121-3129.

"(Phosphine)gold(I)-silyloxides and -silylthiolates"
A. Bauer, W. Schneider, K. Angermaier, A. Schier, H. Schmidbaur, Inorg. Chim. Acta 251, 249-254 (1996).

"A Density Functional Study of Trigold Oxonium Complexes and of Their Dimerization"
S.-C. Chung, S. Krüger, H. Schmidbaur, N. Rösch, Inorg. Chem. 35, 5387-5395 (1996).

"Gold is Smaller than Silver. Crystal Structures of [Bis(trimesitylphosphine) gold(I)] and [Bis(trimesitylphosphine)silver(I)] Tetrafluoroborate"
A. Bayler, A. Schier, G.A. Bowmaker, H. Schmidbaur, J. Am. Chem. Soc. 118, 7006-7007 (1996).

"Gold Clustering at the Methylthiolate Anion"
A. Sladek, K. Angermaier, H. Schmidbaur, J. Chem. Soc., Chem. Commun. 1996, 1559-1960.

"The Auration of Dimethylsulfide"
A. Sladek, H. Schmidbaur, Z. Naturforsch. 51b, 1207-1209 (1996).

"Propeller Isomerism in Bis(trimesitylphosphine)gold(I), -silver(I), and -copper(I) Tetrafluoroborates"
A. Bayler, G.A. Bowmaker, H. Schmidbaur, Inorg. Chem. 35, 5959-5960 (1996).

"Self-Assembly of [(Me2PhP)2Au]+[Au(GeCl3)2]- into Linear Ion Quadruples with an Unusual [+ - - +] Sequence"
A. Bauer, H. Schmidbaur, J. Amer. Chem. Soc. 118, 5324-5325 (1996).

"(Isocyanide)gold(I) Thiosalicylates: Supramolecular Assembly Based on both Auriophilic and Hydrogen Bonding"
W. Schneider, A. Bauer, H. Schmidbaur, Organometallics 15, 5445-5446 (1996).

"Mixed Co-ordination numbers and geometries of gold(I) in a dinuclear complex of thioglycerol"
J.M. Lopez-de-Luzuriaga, A. Sladek, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1996, 4511-4512.

"Bridging of Trigoldsulfonium Clusters by a Silver(I) Ion"
A. Sladek, H. Schmidbaur, Z. Naturforsch. 52b, 301-303 (1997).

"Bis- and tris-(trichlorogermyl)gold(I) anions in their salts with cyclic dications [Au2(Ph2PCH2PPh2)2]2+ and [Au2(Ph2PCH2CH2PPh2]2+"
A. Bauer, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1997, 1115-1116.

"First Example of Linear Strings of Equidistant Gold Atoms in Crystals of [(2,4,6-Me3C6H2NC)2Au][Au(GeCl3)2] "
A. Bauer, W. Schneider, H. Schmidbaur, Inorg. Chem. 36, 2225-2226 (1997).

"An ab initio study of the aggregation of LAuX molecules and [LAuL]+[XAuX]- ions"
P. Pyykkö, W. Schneider, A. Bauer, A. Bayler, H. Schmidbaur, J. Chem. Soc., Chem. Commun. 1997, 1111-1112.

"Facile Preparation and Crystal Structure of [Bis(diphenylphosphino)-amine]digold Dichloride"
P. Lange, A. Schier, H. Schmidbaur, Z. Naturforsch. 52b, 769-771 (1997).

"Aggregation of a Neutral Gold(I) Complex through Cooperative Action of Hydrogen Bonding and Auriophilicity"
C. Hollatz, A. Schier, H. Schmidbaur, J. Amer. Chem. Soc. 119, 8115-8116 (1997).

"Tris(phenylthiomethyl)phosphane Sulfide and Selenide, (PhSCH2)3PX (X = S, Se) as Ambidentate Ligand Systems in Copper(I) Complexes"
S. Fuchs, K. Angermaier, A. Bauer, H. Schmidbaur, Chem. Ber. 130, 105-111 (1997).

"Synthesis of Hexakis[(triphenylphosphane)gold(I)]methanium(2+) Cation from Trimethylsilyldiazomethane; Crystal Structure Determination of the Tetrafluoro- borate Salt"
F.P. Gabbaï, A. Schier, J. Riede, H. Schmidbaur, Chem. Ber. 130, 111-115 (1997).

"Synthesis and Structure of Binuclear Single-Bridged Bis[(phosphane)gold(I)]-halogenonium Complexes"
A. Bayler, A. Bauer, H. Schmidbaur, Chem. Ber. 130, 115-119 (1997).

"Gold(I) Complexes of Chiral Secondary Phosphines"
K. Angermaier, A. Sladek, H. Schmidbaur, Z. Naturforsch. 51b, 1671-1675 (1996).

"Polygold(1-adamantyl)ammonium Salts"
J.M. López-de-Luzuriaga, A. Schier, H. Schmidbaur, Chem. Ber./Recueil 130, 221-223 (1997).

"Gold(I) Complexes of Chiral Secondary Phosphines"
K. Angermaier, A. Sladek, H. Schmidbaur, Z. Naturforsch. 51b, 1671-1674 (1996).

"Synthesis, isomerism and supramolecular chemistry of diphenylmethanimine complexes of the coinage metals"
W. Schneider, A. Bauer, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1997, 415-420.

"Tris(dimethylamino)phosphane as a New Ligand in Gold(I) Chemistry: Synthesis and Crystal Structures of [(Me2N)3]AuCl, {[(Me2N)3PAu]3O}+ BF4-, {[(Me2N)3PAu]3NP(NMe2)3}2+ {BF4-}2 and the Precursor Molecule (Me2N)3PNSiMe3"
A. Bauer, N.W. Mitzel, A. Schier, D.W.H. Rankin, H. Schmidbaur, Chem. Ber./Recueil, 130, 323-328 (1997).

"Structural Investigation of Bis(isonitrile)gold(I) Complexes"
W. Schneider, A. Sladek, A. Bauer, K. Angermaier, H. Schmidbaur, Z. Naturforsch. 52b, 53-56 (1997).

"2-(Diphenylphosphino)-pyridine as an Ambidentate Ligand in Homo- and Hetero-binuclear Complexes of Copper, Silver, and Gold"
M.E. Olmos, A. Schier, H. Schmidbaur, Z. Naturforsch. 52b, 203-208 (1997).

"Gold(I) Complexes of Open-chain and Cyclic Di-secondary Amines"
J.M. López-de-Luzuriaga, M. Söldner, A. Schier, H. Schmidbaur, Z. Naturforsch. 52b, 209-213 (1997).

"Gold Coordination by a Tertiary Phosphine with Three Thioether Functions"
S. Fuchs, J.M. López-de-Luzuriaga, M.E. Olmos, A. Sladek, H. Schmidbaur, Z. Naturforsch. 52b, 217-220 (1997).

"Diphenyl(1-pyridyl)phosphine Sulfide as a Ligand in Mono- and Binuclear Coinage Metal Complexes"
M.E. Olmos, A. Schier, H. Schmidbaur, Z. Naturforsch. 52b, 385-390 (1997).

"A Density Functional Study of Metal-Ligand Bonding in [(PR3)2M]+ and [PR3MCl] (M = Ag, Au; R = H, Me) Complexes"
G.A. Bowmaker, H. Schmidbaur, S. Krüger, N. Rösch, Inorg. Chem. 36, 1754-1757 (1997).

"Polynuclear Gold(I) Complexes of Functionalized Thiols and Dithiols"
J.M. Lopéz-de-Luzuriaga, A. Sladek, W. Schneider, H. Schmidbaur, Chem. Ber./Recueil 130, 641-646 (1997).

"Gold Coordination by 2-(Diphenylphosphanyl)aniline"
J.M. Lopéz-de-Luzuriaga, A. Schier, H. Schmidbaur, Chem. Ber./Recueil 130, 647-650 (1997).

"Gold Clustering at the Terminal Functions of Long-Chain Thiols and Amines "
J.M. López-de Luzuriaga, A. Sladek, A. Schier, H. Schmidbaur, Inorg. Chem. 36, 966-968 (1997).

"Gold Coordination by Tertiary Phosphane Sulfides"
M. Preisenberger, A. Bauer, H. Schmidbaur, Chem. Ber. / Recueil 130, 955-958 (1997).

"Neutral Gold(I) Complexes with Mixed Phosphorus Ligands"
C. Hollatz, A. Schier, H. Schmidbaur, Chem. Ber. / Receuil 130, 1333-1338 (1997).

"Covalent radii of four-co-ordinate copper(I), silver(I) and gold(I): crystal structures of [Ag(AsPh3)4]BF4 and [Au(AsPh3)4]BF4"
U.M. Tripathi, A. Bauer, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1997, 2865-2868.

"Tetramethylguanidine and Benzophenoneimine as Ligands in Gold Chemistry"
W. Schneider, A. Bauer, A. Schier, H. Schmidbaur, Chem. Ber. / Recueil 130, 1417-1422 (1997).

"Gold(I) Complexes of Ketiminophosphanes and -phosphane Sulfides"
W. Schneider, A. Bauer, A. Schier, H. Schmidbaur, Chem. Ber. / Recueil 130, 1423-1426 (1997).

"[(N,N',N''-tricyclohexyl)-N''-cyclohexylcarbamoylguanidinium] Tetrachloro- aurate(III) as a Product of the Reaction of Dicyclohexylcarbodiimide with HAuCl4aq"
W. Schneider, A. Bauer, H. Schmidbaur, Z. Naturforsch. 52b, 1152-1154 (1997).

"A Novel Anionic Gold-Indium Cluster Compound: Synthesis and Molecular and Electronic Structure"
F.P. Gabbaï, S.-C. Chung, A. Schier, S. Krüger, N. Rösch, H. Schmidbaur, Inorg. Chem. 36, 5699-5705 (1997).

"Gold(I) dimethyl- and diphenyl-dithiophosphinate complexes"
M. Preisenberger, A. Bauer, A. Schier, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1998, 4753-4758.

"Chiral Phosphine Ligands in the Structural Chemistry of Gold"
A. Bayler, A. Bauer, H. Schmidbaur, Z. Naturforsch. 52b, 1477-1483 (1997).

"Different Connectivities in Supramolecular Aggregates of Trinuclear Gold(I) Complexes with the Sacconi-Ligand N(CH2CH2PPh2)3"
J. Zank, A. Schier, H. Schmidbaur, Z. Naturforsch. 52b, 1471-1476.

"(Triphenylarsine)gold(I) Complexes: Synthesis of an Oxonium Salt and Redistribution of the Arsine Ligands"
U.M. Tripathi, A. Schier, H. Schmidbaur, Z. Naturforsch. 53b, 171-174 (1998).

"Gold Clustering at Hydroxylamine"
U.M. Tripathi, W. Scherer, A. Schier, H. Schmidbaur, Inorg. Chem. 37, 174-175 (1998).

"Aurophilicity-impaired internal molecular motion of trinuclear gold(I) complexes"
J. Zank, A. Schier, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1998, 323-324.

"Self-assembly of tripodal tris(diphenylphosphinito)fluoroborate ligands in trinuclear gold(I) complexes"
C. Hollatz, A. Schier, H. Schmidbaur, Inorg. Chem. Commum. 1, 115-117 (1998).

"Variations in the Chain Structure of Cationic (Phosphine)gold(I) Dialkyldithiophosphate Complexes"
M. Preisenberger, A. Schier, H. Schmidbaur, Z. Naturforsch. 53b, 781-787 (1998).

"The Trichlorogermanite(II) Anion and ist Gold(I) Complexes"
U.M. Tripathi, G.L. Wegner, A. Schier, A. Jockisch, H. Schmidbaur, Z. Naturforsch. 53b, 939-945 (1998).

"Four-Coordinate Gold(I), Silver(I), and Copper(I) Complexes with a Large-Span Chiral Ditertiary Phosphine Ligand"
A. Bayler, A. Schier, H. Schmidbaur, Inorg. Chem. 37, 4353-4359 (1998).

"Gold and silver cations in the 'Procrustean Bed' of the bis[2-(diphenylphosphino)phenyl]phenylphosphine ligand. Observations and conclusions"
J. Zank, A. Schier, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1999, 415-420.

"Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes"
C. Hollatz, A. Schier, H. Schmidbaur, Z. Naturforsch. 54b, 30-37 (1999).

"(Trimethylphosphine)(triphenylsilyl)gold(I) and Related Compounds"
M. Monge Oroz, A. Schier, H. Schmidbaur, Z. Naturforsch. 54b, 26-29 (1999).

"Self-assembly of triatomic gold units as supporting frames for a large gold diphenylphosphinite cage molecule"
C. Hollatz, A. Schier, J. Riede, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 1999, 111-113.

"The Structural Chemistry of Gold(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines"
B.-C. Tzeng, J. Zank, A. Schier, H. Schmidbaur, Z. Naturforsch. 54b, 825-831 (1999).

"Crystal Engineering of Gold(I) Thiolate Based Compounds via Cooperative Aurophilic and Hydrogen-Bonding Interactions"
B.-C. Tzeng, A. Schier, H. Schmidbaur, Inorg. Chem. 38, 3978-3984 (1999).

"Isomerism of Aurated Phosphine Sulfides, Thiophosphinates, Thiophosphonates, and Thiophosphates: Structural and Quantum Chemical Studies"
M. Preisenberger, P. Pyykk, A. Schier, H. Schmidbaur, Inorg. Chem. 38, 5870-5875 (1999).

"The Distorted Structure of [Au(GeCl3)3]2-"
P. Schwerdtfeger, H. Schmidbaur, Z. Anorg. Allg. Chem. 626, 374-380 (2000).

"The Elusive Structures of Pentakis[(triphenylphosphine)gold]ammonium(2+) Bis[tetrafluoroborate(1-)"
A. Schier, A. Grohmann, J.M. Lpez-de-Luzuriaga, H. Schmidbaur, Inorg. Chem.39, 547-554 (2000).

"Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphos-phine)gold(I) Bis(trimethylsilyl)amide"
G.L. Wegner, A. Jockisch, A. Schier, H. Schmidbaur, Z. Naturforsch. 55b, 347-351 (2000).

"Gold(I) complexes with P=O and P-OH functionalised phosphorus ligands"
C. Hollatz, A. Schier, H. Schmidbaur, Inorg.Chim. Acta 300-302, 191-199 (2000).

"The solid state aggregation of two gold(I) nitrate complexes"
T. Mathieson, A. Schier, H. Schmidbaur, J. Chem. Soc., Dalton Trans. 2000 3881-3884.

"Gold Clustering at Dimethylsulfoximine Me2S(OH)NH"
A. Hamel, C.Hollatz, A. Schier, H. Schmidbaur,Z. Naturforsch. 55b, 889-894 (2000).

"Tris[(triphenylphosphine)gold(I)]oxonium Dihydrogentrifluoride as the Product of an Attempted Preparation of[(Triphenylphosphine)gold(I)] Fluoride"

T. Mathieson, A. Schier, H. Schmidbaur, Z. Naturforsch. 55b, 1000-1004 (2000).

 

Review Articles:

"Organogold Chemistry"
A. Grohmann, H. Schmidbaur, in "Comprehensive Organometallic Chemistry II", E.W.Abel, F.G.A. Stone, G. Wilkinson (Edts.), Pergamon Press Ltd., Oxford, UK, S.1-56 (1994).

"Gold: Organometallic Chemistry"
H. Schmidbaur, in "Encyclopedia of Inorganic Chemistry", John Wiley & Sons, Ltd., Chichester, S. 1226-1234 (1994).

"Gold-Chemie: ein Eldorado"
H. Schmidbaur, Naturw. Rdsch. 48, 443-451 (1995).

"Ludwig Mond Lecture: High-carat Gold Compounds"
H. Schmidbaur, Chem. Soc. Rev. 24, 391-401 (1995).

"Gold Compounds Containing Group 13 and Heavier Group 14 Elements"
H. Schmidbaur, Gold - Progress in Chemistry, Biochemistry and Technology, H. Schmidbaur (Ed.), Wiley, Chichester, 1999, S. 633-645.

"Organogold Chemistry"
H. Schmidbaur, A. Grohmann, M.E. Olmos, Gold - Progress in Chemistry, Biochemistry and Technology, H. Schmidbaur (Ed.), Wiley, Chichester, 1999, S. 648-745.

"Gold - Progress in Chemistry, Biochemistry and Technology"
H. Schmidbaur (Ed.), Wiley, Chichester, 1999.

"Synthesis and uses of organosilver compounds"
H. Schmidbaur, A. Bayler, The chemistry of organic derivatives of gold and silver, S. Patai, Z. Rappoport (Eds.), Wiley, Chichester, 1999, S 211-226.

"Synthesis and uses of organogold compounds"
H. Schmidbaur, A. Grohmann, M.E. Olmos, A. Schier, The chemistry of organic derivatives of gold and silver, S. Patai, Z. Rappoport (Eds.), Wiley, Chichester, 1999, S 227-311.

"The Aurophilicity Phenomenon: A Decade of Experimental Findings, Theoretical Concepts and Emerging Applications"
H. Schmidbaur, Gold Bulletin 33, 3-9 (2000).

 

Books:

"Gold - Progress in Chemistry, Biochemistry and Technology"
H. Schmidbaur, Editor, John Wiley & Sons, Inc., New York, 1999.

 

 


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Annette Schier, August 2012